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Synteses and characterizaton of coordination compounds of zinc(II) with quinaldinate and pyridine ligands.

Valentina Brzuhalski (2016) Synteses and characterizaton of coordination compounds of zinc(II) with quinaldinate and pyridine ligands.. Diploma thesis.

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    Abstract

    A series of zinc(II) complexes with quinaldinate were prepared and structurally characterized. A starting material, [Zn(kinal)2(MeOH)2], was prepared upon the reaction of zinc(II) acetate with quinaldic acid. The main aim was to replace the coordinated methanol with 4-hydroxymethylpyridine, pyridine, 3-hydroxypyridine or pyridine N-oxide. Reactions with the first two ligands (L=4-hmpy, py) were met with success: [Zn(kinal)2(MeOH)2] + 2L  [Zn(kinal)2L2] + 2MeOH Reactions with 3-hydroxypyridine or pyridine N-oxide resulted in a complex with coordinated water, [Zn(kinal)2(H2O)].

    Item Type: Thesis (Diploma thesis)
    Keywords: zinc(II) acetate, quinaldic acid, methanol, 4-hydroxymethylpyridine, pyridine, 3-hydroxypyridine, pyridine N-oxide, complex
    Number of Pages: 36
    Language of Content: Slovenian
    Mentor / Comentors:
    Mentor / ComentorsIDFunction
    doc. dr. Barbara ModecMentor
    Link to COBISS: http://www.cobiss.si/scripts/cobiss?command=search&base=50126&select=(ID=11203401)
    Institution: University of Ljubljana
    Department: Faculty of Education
    Item ID: 3840
    Date Deposited: 03 Oct 2016 14:35
    Last Modified: 03 Oct 2016 14:35
    URI: http://pefprints.pef.uni-lj.si/id/eprint/3840

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