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Characterization of the products of the copper(II) with quinaldinate reaction with ligands with hydroxyl group

Lea Dezire (2016) Characterization of the products of the copper(II) with quinaldinate reaction with ligands with hydroxyl group. Diploma thesis.

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    Abstract

    Reactions of [Cu(kinal)2(CH3OH)]∙CH3OH (kinal⎼ stands for anion of quinaldic acid with a deprotonated carboxylic group) with an excess of a secondary ligand with a hydroxyl group have resulted in substitution of labile methanol and coordination of new ligand. Two novel coordination compounds of copper(II) were prepared: [Cu(kinal)2(4-hmpy)2], a complex with 4-hydroxymethylpyridine (4-hmpy), and [Cu(kinal)2(Nmea)], a complex with N-methylethanolamine (Nmea). Their compositions and structures were revealed by means of X-ray structure analysis on a single-crystal.

    Item Type: Thesis (Diploma thesis)
    Keywords: coordination compounds, copper(II), quinaldic acid, synthesis
    Number of Pages: 33
    Language of Content: Slovenian
    Mentor / Comentors:
    Mentor / ComentorsIDFunction
    doc. dr. Barbara ModecMentor
    Link to COBISS: http://www.cobiss.si/scripts/cobiss?command=search&base=50126&select=(ID=11196489)
    Institution: University of Ljubljana
    Department: Faculty of Education
    Item ID: 3831
    Date Deposited: 30 Sep 2016 12:59
    Last Modified: 30 Sep 2016 12:59
    URI: http://pefprints.pef.uni-lj.si/id/eprint/3831

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